GCPing is a project mainly written in OBJECTIVE-C and C, it's free.
Game Center Test App.
Test matchmaking and multiplayer via Apple's GameKit APIs.
Requires Game Center compatible devices (OS 4.1+).
GCPing only exposes the problems and cannot solve the fundamental issues with NATs and Firewalls.
Brought to you by Damon Danieli at Z2Live, Inc.