Messaging_sendgrid is a project mainly written in PHP, it's free.
Drupal Messaging wrapper for Sendgrid
This is a Sendgrid wrapper for Drupal Messaging (Drupal 7)
http://sendgrid.com/ http://drupal.org/project/messaging http://github.com/josereyero/messaging
It adds proper headers to provide bulk sending features, but it doesn't actually sends mails through Sendgrid.