Osnap is a project mainly written in ..., it's free.
A simple webcam snapshooter
To run osnap.wlua, you'll need:
On Windows, you can get all this and more by installing Lua for Windows.
Outside of Windows, check your local package manager (which will most likely have packages for Lua) and/or Sourceforge (there are some good tips out there for setting up the files you can get from Sourceforge if you search for them).
Run osnap.wlua with a Lua interpreter like wlua.exe for Windows.
Press the "oh snap" buttons on either side of the frame (or the spacebar) to take a picture. (It will be saved as an epoch-time-named JPEG in the working directory.)
Drag across the center of the preview horizontally (or press the H key) to flip it.
Press F11 to toggle fullscreen.